Effect of organo-modified montmorillonite nanoclay on mechanical,thermal and ablation behavior of carbon fiber/phenolic resin composites

The mechanical, thermal and ablation properties of carbon phenolic (C-Ph) composites (Type-I) rein-forced with different weight percentages of organo-modified montmorillonite (o-MMT) nanoclay have been studied experimentally. Ball milling was used to disperse different weight (wt) percentages (0, 1,2,4,6 wt.％) of nanoclay into phenolic resin. Viscosity changes to resin due to nanoclay was studied. On the other hand, nanoclay added phenolic matrix composites (Type-II) were prepared to study the dispersion of nanoclay in phenolic matrix by small angle X-ray scattering and thermal stability changes to the matrix by thermogravimetric analyser (TGA). This data was used to understand the mechanical, thermal and ablation properties of Type-I composites. Inter laminar shear strength (ILSS), flexural strength and flexural modulus of Type I composites increased by about 29％, 12％and 7％respectively at 2 wt.％ addition of nanoclay beyond which these properties decreased. This was attributed to reduced fiber volume fraction (％Vf) of Type-I composites due to nanoclay addition at such high loadings. Mass ablation rate of Type-I composites was evaluated using oxy acetylene torch test at low heat flux (125 W/cm2) and high heat flux levels (500 W/cm2). Mass ablation rates have increased at both flux levels marginally up to 2 wt.％ addition of nanoclay beyond which it has increased significantly. This is in contrast to increased thermal stability observed for Type-I and Type-Ⅱ composites up to 2 wt.％addition of nanoclay. Increased ablation rates due to nanoclay addition was attributed to higher insulation effi-ciency of nanolcay, which accumulates more heat energy in limited area behind the ablation front and self-propagating ablation mechanisms triggered by thermal decomposition of organic part of nanoclay.     

Fullerene bisadduct stabilizers: The effect of different addition positions on inhibiting the autocatalytic decomposition of nitrocellulose absorbed nitroglycerin

To explore the effect of different positions and number of pyrrolidine bound to the carbon cage on the stabilization effect of fulleropyrrolidine derivatives to nitrocellulose (NC)/nitroglycerine (NG), we synthesized N-(4-methoxy) phenylpyrrolidine-C₆₀ and four different of bis(N-(4-methoxy) phenylpyrrolidine)-C₆₀ compounds through Prato reaction. Their structures were characterized by UV–vis, ¹H NMR, ¹³C NMR, high-resolution mass spectroscopy, and single-crystal X-ray diffraction. Their stabilization effect to NC/NG were investigated using differential scanning calorimetry, methyl violet, vacuum stabilization effect, weight loss, and accelerating rate calorimeter tests. The results indicated these compounds had excellent stabilization effect to NC/NG. The stabilization effect of the fulleropyrrolidine bisadducts to NC/NG is significantly better than that of fulleropyrrolidine monoadduct and C₆₀. Moreover, the position where pyrrolidine binds to fullerene in fulleropyrrolidine bisadducts is different, and its stabilization effect to NC is also different. The stabilization effect order of different bisadduct isomers to nitrocellulose is as follows: e-edge > trans-2> cis-2> trans-3. Electron paramagnetic resonance (EPR) and FT-IR were used to study the stabilization mechanism of fulleropyrrolidine derivatives to NC/NG. The EPR results also show that fulleropyrrolidine bisadducts with different addition sites have different abilities to absorb nitroxide, and their ability is better than that of the monoadduct and C₆₀, which is consistent with the results of stabilization effect performance test.     

An interface shear damage model of chromium coating/steel substrate under thermal erosion load

The Cr-plated coating inside a gun barrel can effectively improve the barrel's erosion resistance and thus increase the service life.However,due to the cyclic thermal load caused by high-temperature gun-powder,micro-element damage tends to occur within the Cr coating/steel substrate interface,leading to a gradual deterioration in macro-mechanical properties for the material in the related region.In order to mimic this cyclic thermal load and,thereby,study the thermal erosion behavior of the Cr coating on the barrel's inner wall,a laser emitter is utilized in the current study.With the help of in-situ tensile test and finite element simulation results,a shear stress distribution law of the Cr coating/steel substrate and a change law of the interface ultimate shear strength are identified.Studies have shown that the Cr coating/steel substrate interface's ultimate shear strength has a significant weakening effect due to increasing temperature.In this study,the interfacial ultimate shear strength decreases from 2.57 GPa(no erosion)to 1.02 GPa(laser power is 160 W).The data from this experiment is employed to establish a Cr coating/steel substrate interface shear damage model.And this model is used to predict the flaking process of Cr coating by finite element method.The simulation results show that the increase of coating crack spacing and coating thickness will increase the service life of gun barrel.     

基于RTP协议H．264视频流传输QoS保证的研究

提出一个Linux环境下基于RTP/RTCP的H.264视频流传输的方案,在Linux中调用V4L(VideofourLinux)的API函数采集视频流,经X264压缩,RTP/RTCP协议打包进行传输。并通过RTCP的RR(接收方报告)包反馈信息和吞吐量公式来计算近似带宽,以起始帧量化参数start-qp为视频编码的调节参数,由近似带宽来控制视频编码的参数调整,达到控制输出码率的目的,实现对视频传输的QoS(QualityofService)保证。     

光电干扰武器系统C^3I可执行建模研究

基于UML的C3I系统模型的设计结果是对系统的静态表述,而C3I系统的本质是动态的。着色Petri网(Colored Petri Net,CPN)具有强大的描述能力及严密的数学基础和多种分析手段,并且它是可以仿真运行的。提出了从UML产品映射到可用于逻辑、行为和性能方面体系结构评价的CPN可执行模型的方法,先对光电干扰武器系统C3I进行UML建模的一般描述,再详细地阐述了光电干扰武器系统C3I从UML产品映射到CPN建立可执行模型的过程。通过对可执行模型CPN的仿真可对光电干扰武器系统C3I进行完整准确地评价。     

基于SEA的舰载C3I系统防空作战效能评估模型

现代海战中,空中目标对舰艇的威胁越来越大,舰艇的防空作战能力已成为衡量其综合作战能力的主要指标。而C3I系统作为舰艇的指挥中枢,其性能直接决定着舰艇防空作战的成败。根据现代海战中空中目标的武器作战使用方式,并针对SEA方法的要求,提出了评估C3I系统在防空作战时系统效能的三个主要性能量度(MOP),通过分析C3I系统在防空作战时的特点,建立了评估C3I系统防空作战效能的SEA方法模型。并利用该模型比较了不同的C3I系统的作战效能,对结果进行了简要分析,证明了SEA方法模型对舰载防空C3I系统进行效能评估的可行性。     

三坐标雷达目标真实高度估计算法研究

在目标跟踪领域,通过三坐标雷达的测量值(斜距、仰角及方位角)来估算目标的真实高度一直是个难点。目前主要有两类处理方法:坐标转换法和等效地球半径法。前者把与雷达天线相关的三坐标测量值转换到大地坐标系统来计算目标高度;后者充分考虑地球曲率以及大气折射的特性,通过增加地球半径来估算目标的高度。最后对上述的两类方法进行总结、比较与分析。     

一种基于SOAP安全的网络中心发布/订阅机制

针对网络中心发布/订阅系统异步、松散耦合和多对多通信等特点,采用了SOAP消息传递机制对信息进行了封装,从而屏蔽了信息的异构性。考虑到信息传输的可靠性,采用XML-Encryption机制构造SOAP消息,为消息交换和数据传输提供一种安全的保证。实际应用表明该系统在网络中心战中有较好的应用前景。     

聚硅氧烷先驱体转化制备2D Cf/Si-O-C材料

以二维碳纤维布和廉价的聚硅氧烷为原料,采用先驱体转化工艺制备2D Cf/Si-O-C材料,对其力学性能进行了考察,并与以聚碳硅烷为先驱体制备的2D Cf/SiC材料在价格和性能方面进行了对比。实验表明,2D Cf/Si-O-C材料力学性能较2D Cf/SiC材料有所下降,但成本大大降低。2D Cf/Si-O-C材料弯曲强度达到157.9 MPa,断裂韧性达到8.4MPa.m1/2,剪切强度达到23.4MPa,并且在1400℃下能较好保持材料的力学性能。     

参数化滤波器逼近问题的全局最优算法

基于Lipschitz下界估值和分枝定界技术,给出了一维参数化小波滤波器逼近问题的全局最优算法。由于充分利用了滤波器逼近问题的特点,本方法将原来的Lipschitz算法的线性收敛速率提高为二次收敛速率。